Preheat oven to 350°F. Lightly coat a shallow 3-quart baking dish with cooking spray.
In a large pot, combine the sliced potatoes, half-and-half, salt, and cayenne pepper.
Bring mixture to a gentle boil over medium heat, stirring occasionally to prevent sticking.
Once boiling, remove from heat.
Using a slotted spoon, transfer half of the potatoes to the prepared baking dish.
Sprinkle with 1 cup of shredded cheddar cheese and 2 tablespoons of chopped chives.
Top with the remaining potatoes.
Pour the remaining half-and-half mixture evenly over the potatoes.
Sprinkle with the remaining cheddar cheese.
Bake for 45–50 minutes, or until the potatoes are tender and the top is golden brown and bubbly.
Remove from oven and sprinkle with the remaining 2 tablespoons of fresh chives before serving.